Optimizing Atomic Neighborhoods for Speedier Chemical Reactions

Clusters with longer separations between atoms had enhanced catalytic activity.

Image courtesy of Central Michigan University and SUNY at Binghamton
Palladium-nickel nanoparticles (top structural model) are synthesized and then exposed to reactive gases (lower right) while being probed with high-energy x-rays.  The x-ray scattering pattern (lower left) is used to refine the structural model and direct further synthesis and post-synthesis treatment toward an optimal atomic neighborhood for nanoparticle surfaces.

The Science

Scientists have discovered that for palladium-nickel catalysts, certain surface characteristics, measured at the atomic level, sped the creation of carbon dioxide from carbon monoxide. To reveal the optimal atomic neighborhood for surface chemical activity, high-energy x-rays were scattered by nanoparticles while they were exposed to a reactive chemical environment.

The Impact

Catalysts accelerate chemical reactions and are essential to efficient industrial processes involved in energy production and pollution control.  Employing in-operation tools to atomic-level interactions in palladium-based catalysts enhances the discovery and design cycles necessary for engineering low-cost, highly active, and stable catalysts.

Summary

Palladium-nickel nanoalloy catalysts have tunable parameters, such as particle size and atomic composition, that affect critical atomic-scale structural features.  These key structural features include local bond distances and number of neighbors at surface sites, and are correlated with catalytic activity for the conversion of carbon monoxide into carbon dioxide. Surface sites with more atomic neighbors and longer first-neighbor separations were found to be more active catalytically than those with fewer atomic neighbors and shorter first-neighbor separations. This type of atomic detail has not been available by traditional studies and can aid the cycle of catalyst design by optimizing for structural parameters at the nearest neighbor level of an atomic environment.  The atomic detail in a reactive environment was made possible by x-ray scattering techniques that involve high-energy x-rays and bright synchrotron x-ray beams able to penetrate sealed reaction chambers and resolve positions of atoms with high precision in minute amounts of nanoalloy particles. The work also demonstrated how various thermal and chemical environmental pathways alter the atomic neighborhood of nanoparticle surfaces.

Contact

Valeri Petkov
Central Michigan University
petko1vg@cmich.edu

Chuan-Jian Zhong
SUNY at Binghamton
cjzhong@binghamton.edu

Funding

DOE Office of Science, Basic Energy Sciences, for both the research and the use of Advanced Photon Source at Argonne National Laboratory.

Publications

S. Shan, V. Petkov, L. Yang, J. Luo, P. Joseph, D. Mayzel, B. Prasai, L. Wang, M. Engelhard, and C.J. Zhong, "Atomic-structural synergy for catalytic oxidation of CO over palladium-nickel nanoalloys," Journal of the American Chemical Society 136 (19), 7140–7151 2014. [DOI: 10.1021/ja5026744]

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